Reductive Elimination from Sterically Encumbered Ni–Polypyridine Complexes
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DOI: 10.1021/acs.organomet.2c00362
Abstract: Herein we disclose the synthesis of sterically encumbered dialkylnickel(II) complexes bearing 2,9-dimethyl-1,10-phenanthroline ligands. A comparison with their unsubstituted analogues by both X-ray crystallography and theoretical calculations revealed significant distortions in their molecular structures. Eyring plots… read more here.
Keywords: encumbered polypyridine; elimination sterically; polypyridine complexes; sterically encumbered ... See more keywords