Influence of mole-ratio on the coordination behaviour of a ditopic N2O2S2-macrocycle: endo/exocyclic silver(I) coordination polymer exhibiting desolvation-induced SCSC transformation
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DOI: 10.1039/c7ce01540b
Abstract: Mole-ratio dependent formations of the macrocyclic silver(I) complexes with different coordination modes and topologies are reported. When one equivalent of AgPF6 was reacted with an N2O2S2-macrocycle (L), a typical endocyclic monomer complex [Ag(L)]PF6 (1) was… read more here.
Keywords: coordination; n2o2s2 macrocycle; mole ratio; endo exocyclic ... See more keywords
Endocyclic and Endo–Exocyclic Silver(I) Complexes of Thiaoxaaza Macrocycles: Crystallographic and NMR Studies
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DOI: 10.1071/ch16467
Abstract: A comparative investigation of the coordination behaviour of a 19-membered NO2S2-macrocycle (L1) and a 20-membered NO2S3-macrocycle (L2) is reported. On silver(i) complexation, L1 yields a discrete endocyclic mononuclear complex, whereas L2 affords a one-dimensional coordination… read more here.
Keywords: exocyclic silver; coordination; endocyclic endo; silver complexes ... See more keywords