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Published in 2017 at "Inorganic chemistry frontiers"
DOI: 10.1039/c7qi00209b
Abstract: We report the synthesis, characterization and DFT studies of a transition-metal-encapsulated superatom compound, [K(2,2,2-crypt)]3[Au@Pb12]·2py, which adopts a distorted symmetry instead of the icosahedral structure due to the second-order Jahn–Teller effect. DFT computations revealed its chemical…
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Keywords:
endohedral plumbaspherene;
characterization electronic;
electronic properties;
properties endohedral ... See more keywords