Expanding the Biocatalytic Toolbox with a New Type of ene/yne‐Reductase from Cyclocybe aegerita
Sign Up to like & getrecommendations! Published in 2021 at "ChemCatChem"
DOI: 10.1002/cctc.202002011
Abstract: This study introduces a new type of ene/yne‐reductase from Cyclocybe aegerita with a broad substrate scope including aliphatic and aromatic alkenes/alkynes from which aliphatic C8‐alkenones, C8‐alkenals and aromatic nitroalkenes were the preferred substrates. By comparing… read more here.
Keywords: reduction; new type; reductase; type ene ... See more keywords
Electronic, optical and thermal properties of highly stretchable 2D carbon Ene-yne graphyne
Sign Up to like & getrecommendations! Published in 2017 at "Carbon"
DOI: 10.1016/j.carbon.2017.07.066
Abstract: Abstract Recently, a new carbon-based two-dimensional (2D) semiconducting material, so called carbon Ene-yne (CEY), was successfully synthesized. In this work, we examine electronic, optical and thermal properties of this novel material. We studied the stretchability… read more here.
Keywords: cey; carbon ene; electronic optical; ene yne ... See more keywords
Fluoroalkyl-functional imidazoles and imidazolium–based ionic liquids prepared via thiol-ene/yne click chemistry
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2019.111677
Abstract: Abstract A fluorinated thiol was systematically investigated against a diverse set of –ene- and –yne-bearing imidazole and imidazolium substrates in the pursuit of new cation-fluorinated, omniphobic (hydrophobic and oleophobic) ionic liquids for aerospace applications. Compounds… read more here.
Keywords: click chemistry; chemistry; ene yne; fluoroalkyl functional ... See more keywords
Mixing End Groups in Thiol-Ene/Yne Reactions as a Simple Approach toward Multienzyme-Responsive Polymeric Amphiphiles
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DOI: 10.1055/s-0037-1611340
Abstract: Taking advantage of the high fidelity of thiol-ene and thiol-yne chemistries, we used mixtures of thiols to prepare degradable PEG-dendron amphiphiles functionalized with two different types of enzymatically cleavable end groups. By tuning the feed… read more here.
Keywords: mixing end; groups thiol; ene yne; thiol ene ... See more keywords
Synthesis and Cytotoxicity of Selenium-Containing Dienones
Sign Up to like & getrecommendations! Published in 2020 at "Russian Journal of General Chemistry"
DOI: 10.1134/s1070363220020085
Abstract: Abstract The nucleophilic addition of benzoselenol occurs regioselectively at the β-carbon of the triple bond of 1,5-disubstituted pent-2-ene-4-yne-1-ones, pent-4-ene-2-yne-1-ones and pent-1-ene-4-yne-3-ones. The resulting selenium-containing conjugated dienones exhibit pronounced cytotoxicity against some tumor cell lines. read more here.
Keywords: cytotoxicity; selenium containing; ene yne; pent ene ... See more keywords
Recent Advances in Visible-Light Photoredox Catalysis for the Thiol-Ene/Yne Reactions
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27030619
Abstract: Visible-light photoredox catalysis has been established as a popular and powerful tool for organic transformations owing to its inherent characterization of environmental friendliness and sustainability in the past decades. The thiol-ene/yne reactions, the direct hydrothiolation… read more here.
Keywords: photoredox catalysis; light photoredox; thiol ene; ene yne ... See more keywords