Articles with "enforcing steric" as a keyword



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Taming the Chlorine Radical: Enforcing Steric Control over Chlorine-Radical-Mediated C-H Activation.

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Published in 2022 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.1c13333

Abstract: Chlorine radicals readily activate C-H bonds, but the high reactivity of these intermediates precludes their use in regioselective C-H functionalization reactions. We demonstrate that the secondary coordination sphere of a metal complex can confine photoeliminated… read more here.

Keywords: chlorine radical; enforcing steric; taming chlorine; radical enforcing ... See more keywords