Theoretical Insights into the Mechanism and Stereoselectivity of Olefin Cyclopropanation Catalyzed by Two Engineered Cytochrome P450 Enzymes.
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DOI: 10.1021/acs.inorgchem.8b01875
Abstract: Engineered P450s can catalyze some non-natural reactions with high efficiency and excellent selectivity, such as the carbine transfer, nitrene transfer, C-H insertion, and C-H amination, opening alternative routes for sustainable production of chemicals. Recent experiments… read more here.
Keywords: cyclopropanation; two engineered; engineered cytochrome; cytochrome p450 ... See more keywords