Catalytic Enantioselective Amination of Enol Silyl Ethers Using a Chiral Paddle-Wheel Diruthenium Complex.
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DOI: 10.1021/acs.orglett.3c00940
Abstract: A chiral paddle-wheel dinuclear ruthenium catalyst was applied to a catalytic asymmetric nitrene-transfer reaction with enol silyl ethers. The ruthenium catalyst was applicable to aliphatic enol silyl ethers as well as aryl-containing enol silyl ethers.… read more here.
Keywords: chiral paddle; paddle wheel; enol silyl; silyl ethers ... See more keywords