Cobalt(II)–tetraphenylporphyrin-catalysed carbene transfer from acceptor–acceptor iodonium ylides via N-enolate–carbene radicals
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DOI: 10.1038/s41557-022-00905-4
Abstract: Square-planar cobalt(II) systems have emerged as powerful carbene transfer catalysts for the synthesis of numerous (hetero)cyclic compounds via cobalt(III)–carbene radical intermediates. Spectroscopic detection and characterization of reactive carbene radical intermediates is limited to a few… read more here.
Keywords: acceptor; carbene radical; carbene; iodonium ylides ... See more keywords