Stereoselective Decarboxylative Alkylation of Titanium(IV) Enolates with Diacyl Peroxides.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b04148
Abstract: Simple treatment of chiral titanium(IV) enolates with diacyl peroxides produces highly diastereoselective decarboxylative alkylations to efficiently deliver the corresponding adducts, most of which are not accessible through any of the current alkylating procedures. Such an… read more here.
Keywords: titanium enolates; alkylation; stereoselective decarboxylative; diacyl peroxides ... See more keywords