Pseudophedrine-Derived Myers Enolates: Structures and Influence of Lithium Chloride on Reactivity and Mechanism.
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DOI: 10.1021/jacs.9b00328
Abstract: The structures and reactivities of pseudoephedrine-derived dianionic Myers enolates are examined. A combination of NMR and IR spectroscopic, crystallographic, and computational data reveal that the homoaggregated dianions form octalithiated tetramers displaying S4-symmetric Li8O8 cores and… read more here.
Keywords: pseudophedrine derived; myers enolates; derived myers; lithium chloride ... See more keywords