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   Articles with "enthalpy entropy" as a keyword



Extreme enthalpy‒entropy compensation in the dimerization of small solutes in aqueous solution

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recommendations! Published in 2024 at "European Biophysics Journal"

DOI: 10.1007/s00249-024-01722-y

Abstract: This communication summarizes findings from the earliest encounters with extreme enthalpy‒entropy compensation, a phenomenon first detected in the 1950s by a reappraisal of isopiestic and calorimetric measurements on aqueous urea solutions in terms of solute… read more here.

Keywords: usepackage; enthalpy entropy; extreme enthalpy; entropy compensation ... See more keywords

Validation of Enthalpy–Entropy Compensation Mechanism in Partial Amide Bond Rotation

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recommendations! Published in 2020 at "ACS Omega"

DOI: 10.1021/acsomega.0c00332

Abstract: The concept of enthalpy–entropy compensation (EEC) is one of the highly debated areas of thermodynamics. The conformational change due to restricted double-bond rotation shows a classic two-site chemical exchange phenomenon and has been extensively studied.… read more here.

Keywords: entropy compensation; compensation; enthalpy entropy; amide bond ... See more keywords

Bistable organic electrochemical transistors: enthalpy vs. entropy

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recommendations! Published in 2024 at "Nature Communications"

DOI: 10.1038/s41467-024-51001-9

Abstract: Organic electrochemical transistors (OECTs) underpin a range of emerging technologies, from bioelectronics to neuromorphic computing, owing to their unique coupling of electronic and ionic charge carriers. In this context, various OECT systems exhibit significant hysteresis… read more here.

Keywords: transistors enthalpy; organic electrochemical; bistable organic; electrochemical transistors ... See more keywords

On Enthalpy–Entropy Compensation Characterizing Processes in Aqueous Solution

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recommendations! Published in 2025 at "Entropy"

DOI: 10.3390/e27070716

Abstract: The phenomenon of enthalpy–entropy compensation emerges as a ubiquitous feature of processes occurring in water, especially those involving biological macromolecules. In writing the present study, the aim was not to review most of the rationalizations… read more here.

Keywords: enthalpy entropy; compensation characterizing; water; entropy compensation ... See more keywords