Probing the Entropic Effect in Molecular Noncovalent Interactions between Resin-Bound Polybrominated Arenes and Small Substrates.
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DOI: 10.1002/cplu.201800304
Abstract: The associative interaction between resin-bound polybrominated arenes and small molecules was analyzed by using various spectroscopic techniques as well as a synthetic molecular model to establish the thermodynamics. The binding in acetonitrile was three orders… read more here.
Keywords: bound polybrominated; polybrominated arenes; resin bound; probing entropic ... See more keywords
Reaction-mediated entropic effect on phase separation in a binary polymer system
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DOI: 10.1016/j.cplett.2017.07.045
Abstract: Abstract We present a computer simulation to study the phase separation behavior induced by polymerization in a binary system comprising polymer chains and reactive monomers. We examined the influence of interaction parameter between components and… read more here.
Keywords: phase separation; entropic effect; polymer; separation ... See more keywords
Entropic effect of macromolecular crowding enhances binding between nucleosome clutches in heterochromatin, but not in euchromatin
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DOI: 10.1038/s41598-018-23753-0
Abstract: Sharp increase in macromolecular crowding induces abnormal chromatin compaction in the cell nucleus, suggesting its non-negligible impact on chromatin structure and function. However, the details of the crowding-induced chromatin compaction remain poorly understood. In this… read more here.
Keywords: density; effect macromolecular; entropic effect; nucleosome clutches ... See more keywords
Unraveling strongly entropic effect on β -relaxation in metallic glass: Insights from enhanced atomistic samplings over experimentally relevant timescales
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DOI: 10.1103/physrevb.102.174103
Abstract: The Johari-Goldstein secondary $(\ensuremath{\beta})$ relaxation is an intrinsic feature of glasses, which is crucial to many properties of disordered materials. One puzzling feature of $\ensuremath{\beta}$-relaxation is its wide relaxation peak, which could imply a critical… read more here.
Keywords: ensuremath beta; beta relaxation; entropic effect; relaxation ... See more keywords