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   Articles with "entropy driven" as a keyword



Entropy‐Driven Self‐Healing of Metal Oxides Assisted by Polymer–Inorganic Hybrid Materials

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recommendations! Published in 2022 at "Advanced Materials"

DOI: 10.1002/adma.202202989

Abstract: Enabling self‐healing of materials is crucially important for saving resources and energy in numerous emerging applications. While strategies for the self‐healing of polymers are advanced, mechanisms for semiconducting inorganic materials are scarce due to the… read more here.

Keywords: entropy driven; self healing; healing metal; metal oxides ... See more keywords

Entropy‐Driven Stabilization of Noble Metal Single Atoms: Advancing Ammonia Synthesis and Energy Output in Zinc‐Nitrate Batteries

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recommendations! Published in 2025 at "Advanced Materials"

DOI: 10.1002/adma.202500224

Abstract: Noble metal single atoms (NMSA) offer exceptional atom utilization and catalytic activity but face challenges like limited stability, low atomic loading, and complex synthesis. This study presents an innovative entropy‐driven strategy to stabilize Ru single… read more here.

Keywords: single atoms; entropy driven; noble metal; zinc nitrate ... See more keywords

Entropy-Driven Ring-Opening Disulfide Metathesis Polymerization for the Synthesis of Functional Poly(disulfide)s.

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recommendations! Published in 2018 at "Macromolecular rapid communications"

DOI: 10.1002/marc.201700735

Abstract: Metal-free entropy-driven disulfide metathesis polymerization of unsaturated l-cystine based macrocycles produces high-molar-mass heterofunctional poly(disulfide)s, i.e., poly(ester-disulfide-alkene) and poly(amide-disulfide-alkene); Mwapp = 44-60 kDa, Ð > 1.7. The polymerization is fast and reaches equilibrium within 1-5 minutes… read more here.

Keywords: metathesis polymerization; polymerization; entropy driven; poly ... See more keywords

Entropy-Driven 60 mol% Li Electrolyte for Li Metal-Free Batteries.

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recommendations! Published in 2024 at "Small"

DOI: 10.1002/smll.202405007

Abstract: Highly Li-concentrated electrolytes are acknowledged for their compatibility with Li metal negative electrodes and high voltage positive electrodes to achieve high-energy Li metal batteries, showcasing stable and facile interfaces for Li deposition/dissolution and high anodic… read more here.

Keywords: mol electrolyte; metal free; metal; entropy driven ... See more keywords

Proximity ligation assay induced hairpin to DNAzyme structure switching for entropy-driven amplified detection of thrombin.

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recommendations! Published in 2019 at "Analytica chimica acta"

DOI: 10.1016/j.aca.2019.03.007

Abstract: A proximity ligation assay (PLA) induced hairpin to DNAzyme structure switching strategy has been described for entropy-driven amplified detection of thrombin. The enzyme-strand (E-DNA) and substrate-strand (S-DNA) of DNAzyme are locked in hairpins structure, and… read more here.

Keywords: dnazyme; proximity ligation; entropy driven; structure ... See more keywords

Entropy-driven melting point depression in fcc HEAs

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recommendations! Published in 2022 at "Scripta Materialia"

DOI: 10.1016/j.scriptamat.2021.114336

Abstract: Abstract High Entropy Alloys (HEAs) are an increasingly dominant alloy design paradigm. The premise of entropic stabilization of single-phase alloys has motivated much of the research on HEAs. Chemical complexity may indeed help stabilize single… read more here.

Keywords: fcc heas; entropy driven; melting point; point depression ... See more keywords
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Programmable DNA Circuits for Flexible and Robust Exciton-Plasmon Interaction-Based Photoelectrochemical Biosensing.

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recommendations! Published in 2021 at "Analytical chemistry"

DOI: 10.1021/acs.analchem.1c02488

Abstract: DNA circuits as one of the dynamic nanostructures can be rationally designed and show amazing geometrical complexity and nanoscale accuracy, which are becoming increasingly attractive for DNA entropy-driven amplifier design. Herein, a novel and elegant… read more here.

Keywords: dna circuits; entropy driven; dna; exciton plasmon ... See more keywords

A Photoresponsive and Metal-Organic Framework Encapsulated DNA Tetrahedral Entropy-Driven Amplifier for High-Performance Imaging Intracellular MicroRNA.

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recommendations! Published in 2021 at "Analytical chemistry"

DOI: 10.1021/acs.analchem.1c04105

Abstract: The further development of high-performance fluorescent biosensors to image intracellular microRNAs is beneficial to cancer medicine. By virtue of the need for enzymes and hairpin DNA probes, the entropy-driven reaction-assisted signal amplification strategy has shown… read more here.

Keywords: high performance; dna; entropy driven; performance ... See more keywords

Construction of an Entropy-Driven Dumbbell-Type DNAzyme Assembly Circuit for Lighting Up Uracil-DNA Glycosylase in Living Cells.

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recommendations! Published in 2022 at "Analytical chemistry"

DOI: 10.1021/acs.analchem.2c03223

Abstract: Sensitive monitoring of intracellular uracil-DNA glycosylase (UDG) in living cells is essential to understanding the DNA repair pathways and discovery of anticancer drugs. Herein, we demonstrate the construction of an entropy-driven dumbbell-type DNAzyme assembly circuit… read more here.

Keywords: dna; entropy driven; dnazyme; uracil dna ... See more keywords

Entropy-Driven Self-Assembly of Single Quantum Dot Sensor for Catalytic Imaging of Telomerase in Living Cells.

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recommendations! Published in 2022 at "Analytical chemistry"

DOI: 10.1021/acs.analchem.2c04747

Abstract: Telomerase is a highly valuable cancer diagnosis biomarker and a promising cancer therapy target. So far, most telomerase assays are limited by the involvement of tedious procedures, multiple enzymes, and complicated reaction schemes. Sensitive monitoring… read more here.

Keywords: imaging telomerase; telomerase; entropy driven; telomerase living ... See more keywords

Accelerating Cell-Free Biosensors by Entropy-Driven Assembly of Transcription Templates.

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recommendations! Published in 2023 at "Analytical chemistry"

DOI: 10.1021/acs.analchem.3c01090

Abstract: Due to its high efficiency and selectivity, cell-free biosynthesis has found broad utility in the fields of bioproduction, environment monitoring, and disease diagnostics. However, the practical application is limited by its low productivity. Here, we… read more here.

Keywords: entropy driven; driven assembly; transcription; cell free ... See more keywords