Enzymatic N N bond formation: Mechanism for the N-nitroso synthesis catalyzed by non-heme iron SznF enzyme
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DOI: 10.1016/j.jcat.2021.04.010
Abstract: Abstract Enzymatic N-N bond formation is rare. Herein, the mechanism for the N-nitrosation from Nδ-hydroxy-Nω-hydroxy-Nω-methyl-L-arginine (L-HMA) catalyzed by SznF, a non-heme iron enzyme, has been illustrated, using density functional calculations. The reaction proceeds through the… read more here.
Keywords: bond formation; non heme; enzymatic bond; bond ... See more keywords