Mechanistic kinetic modelling of enzyme-catalysed oxidation reactions of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA)
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Science"
DOI: 10.1016/j.ces.2021.116982
Abstract: Abstract Six enzymes were tested against HMF and its oxidation intermediates to determine substrate specificity, product yield and pathways. A Michaelis–Menten kinetic mathematical model was constructed and some rate parameters calculated. The best 2,5-diformylfuran (DFF)… read more here.
Keywords: enzyme reactions; oxidation; dff; mechanistic kinetic ... See more keywords
Controlling enzyme reactions by supramolecular protection and deprotection of oligosaccharide substrates.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03239b
Abstract: Protection/deprotection is a powerful strategy in the total synthesis of complex organic molecules but similar tools are nearly absent in enzymatic reactions. We here report supramolecular protective receptors that outcompete an enzyme in the binding… read more here.
Keywords: enzyme reactions; protection; protection deprotection; reactions supramolecular ... See more keywords
Trimethyl-Substituted Carbamate as a Versatile Self-Immolative Linker for Fluorescence Detection of Enzyme Reactions
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DOI: 10.3390/molecules25092153
Abstract: Self-immolative linker is a useful building block of molecular probes, with broad applications in the fields of enzyme activity analysis, stimuli-responsive material science, and drug delivery. This manuscript presents N-methyl dimethyl methyl (i.e., trimethyl) carbamate… read more here.
Keywords: immolative linker; fluorescence; enzyme reactions; self immolative ... See more keywords