Visible Light-Mediated, Diastereoselective Epimerization of Morpholines and Piperazines to More Stable Isomers.
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DOI: 10.1021/acscatal.2c03672
Abstract: We report a photocatalyzed epimerization of morpholines and piperazines that proceeds by reversible hydrogen atom transfer (HAT) and provides an efficient strategy for editing the stereochemical configurations of these saturated nitrogen heterocycles, which are prevalent… read more here.
Keywords: epimerization; epimerization morpholines; morpholines piperazines; visible light ... See more keywords