Proton-accelerated Lewis acid catalysis for stereo- and regioselective isomerization of epoxides to allylic alcohols.
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DOI: 10.1039/d1cc02840e
Abstract: The isomerization of epoxides to allylic alcohols was developed via proton-accelerated Lewis acid catalysis. The addition of tBuOH as a proton source is the key to the efficient catalytic cycle. Trisubstituted epoxides, including enantioenriched derivatives,… read more here.
Keywords: lewis acid; isomerization epoxides; allylic alcohols; epoxides allylic ... See more keywords