Effects of strong coordination bonds at the axial or equatorial positions on magnetic relaxation for pentagonal bipyramidal dysprosium(III) single-ion magnets.
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DOI: 10.1039/d2dt02402k
Abstract: Three pentagonal bipyramidal mononuclear Dy(III) complexes based on amino-substituted nitrophenol and tetradentate amide ligands of formulas [Dy(Hbpen)(OPhNO2NH2Cl)Cl2] (1), [Dy(Hbpen)(OPhNO2NH2)Cl2] (2) and [Dy(Hbpen)(OPhNO2NH2Cl)3] (3) (Hbpen = N,N'-bis(2-pyridylmethyl)-ethylenediamine, OPhNO2NH2Cl = 2-amino-6-chloro-4-nitrophenol, and OPhNO2NH2 = 2-amino-4-nitrophenol) were isolated.… read more here.
Keywords: ion magnets; coordination; equatorial positions; single ion ... See more keywords