LAUSR

Equatorial restriction of the photoinduced Jahn-Teller switch in Mn(III)-cyclam complexes

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2 Published in 2023 at "Chemical Science"

DOI: 10.1039/d3sc01506h

Abstract: Ultrafast transient absorption spectra were recorded for solutions of [MnIII(cyclam)(H2O)­(OTf)][OTf]2 (cyclam = 1,4,8,11-tetraazacyclotetradecane and OTf = Trifluoromethanesulfonate) in water to explore the possibility to restrict the equatorial expansion following photoexcitation... read more here.

Keywords: cyclam; photoinduced jahn; equatorial restriction; restriction photoinduced ... See more keywords