Evaluating the energy landscape of an out-of-equilibrium bistable [2]rotaxane containing monopyrrolotetrathiafulvalene.
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DOI: 10.1039/d3cc00360d
Abstract: The unique redox properties of monopyrrolotetrathiafulvalene can be used to induce directional movement in interlocked molecules. In this study, the kinetics for the directional movement of cyclobis(paraquat-p-phenylene) across the dioxidised monopyrrolotetrathiafulvalene in a [2]rotaxane is… read more here.
Keywords: equilibrium bistable; rotaxane; monopyrrolotetrathiafulvalene; energy landscape ... See more keywords