Synthesis of diethyl carbonate from ethanol through different routes: A thermodynamic and comparative analysis
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DOI: 10.1002/cjce.22896
Abstract: In this study, thermodynamic analysis of various possible synthesis routes of diethyl carbonates (DEC), a benign organic carbonate, was carried out and a comparative analysis was performed. Chemical equilibrium constants at standard conditions were calculated… read more here.
Keywords: comparative analysis; equilibrium constants; equilibrium; route ... See more keywords
Determination of equilibrium constants of iron(iii)-1,2-dihydroxybenzene complexes and the relationship between calculated iron speciation and degradation of rhodamine B
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DOI: 10.1039/d1nj01579f
Abstract: The contribution of the monocomplex [Fe(DHB)]+ to the percentage of rhodamine B degradation is statistically significant. read more here.
Keywords: degradation; equilibrium constants; determination equilibrium; constants iron ... See more keywords
Species-Specific, pH-Independent, Standard Redox Potential of Selenocysteine and Selenocysteamine
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DOI: 10.3390/antiox9060465
Abstract: Microscopic redox equilibrium constants and standard redox potential values were determined to quantify selenolate-diselenide equilibria of biological significance. The highly composite, codependent acid-base and redox equilibria of selenolates could so far be converted into pH-dependent,… read more here.
Keywords: equilibrium constants; standard redox; redox potential; redox ... See more keywords