A formal synthesis of (-)-erinacine B enabled by asymmetric organocatalysis.
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DOI: 10.1039/d3cc01935g
Abstract: A unified strategy for accessing the core structure of cyathane diterpenoids has been developed, enabling the formal synthesis of (-)-erinacine B. The key feature includes an organocatalyzed asymmetric intramolecular vinylogous aldol reaction for convergently building… read more here.
Keywords: synthesis erinacine; erinacine enabled; formal synthesis; enabled asymmetric ... See more keywords