Mechanistic insights into catalytic carboxylic ester hydrogenation with cooperative Ru(II)-bis{1,2,3-triazolylidene}pyridine pincer complexes
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.01.003
Abstract: Transmetallation of newly designed lutidine-based CNC or CNN ligands L, featuring flanking 1,2,3-triazolylidene (tzNHCs) moieties, from Ag(I) to Ru(II) provided access to well-defined cationic [RuII(CO)(H)(L)(PPh3)]+ complexes 2 and 5. Spectroscopic investigations confirm that, in both… read more here.
Keywords: ester hydrogenation; ester; mechanistic insights; catalytic carboxylic ... See more keywords
Ester Hydrogenation with Bifunctional Metal–NHC Catalysts: Recent Advances
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DOI: 10.1021/acsomega.0c04819
Abstract: Hydrogenation of ester to alcohol is an essential reaction in organic chemistry due to its importance in the production of a wide range of bulk and fine chemicals. There are a number of homogeneous and… read more here.
Keywords: metal nhc; ester hydrogenation; metal; recent advances ... See more keywords