α-Arylation of Esters and Ketones Enabled by a Bench-Stable Pd(I) Dimer Catalyst
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DOI: 10.1055/s-0037-1610087
Abstract: A procedure for the α-arylation of α,α-disubstituted esters and ketones to generate quaternary carbon centers is described. The developed protocol is operationally simple and employs an air- and moisture-stable dinuclear Pd(I) complex [Pd(μ-I)(Pt-Bu3)]2 to mediate… read more here.
Keywords: ketones enabled; bench stable; arylation; arylation esters ... See more keywords