Homoleptic Perchlorophenyl "Ate" Complexes of Thorium(IV) and Uranium(IV).
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DOI: 10.1021/acs.inorgchem.1c01686
Abstract: The reaction of AnCl4(DME)n (An = Th, n = 2; U, n = 0) with 5 equiv of LiC6Cl5 in Et2O resulted in the formation of homoleptic actinide-aryl "ate" complexes [Li(DME)2(Et2O)]2[Li(DME)2][Th(C6Cl5)5]3 ([Li][1]) and [Li(Et2O)4][U(C6Cl5)5] ([Li][2]).… read more here.
Keywords: et2o; ate complexes; homoleptic perchlorophenyl; complexes thorium ... See more keywords