Ethenolysis Without Ethene: A Practical and Safe Lab Method to Introduce Terminal Alkene Groups via Metathesis Exemplified for Chiral Natural Product Chemistry
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DOI: 10.1002/cctc.202500890
Abstract: The introduction of terminal alkene groups through ethenolysis is a well‐established metathesis process. However, while being widely applied in industry, this reaction is not performed without risk in organic synthesis laboratories due to the hazardous… read more here.
Keywords: metathesis; chemistry; ethenolysis; terminal alkene ... See more keywords
Remarkably Efficient Microwave-Assisted Cross-Metathesis of Lipids under Solvent-Free Conditions.
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DOI: 10.1002/cssc.201601824
Abstract: Catalytic transformation of renewable feedstocks into fine chemicals is in high demands and olefin metathesis is a sophisticated tool for biomass conversion. Nevertheless, the large-scale viability of such processes depends on the conversion efficiency, energy… read more here.
Keywords: canola oil; ethenolysis; microwave assisted; cross metathesis ... See more keywords
Looking for the Noncyclic(amino)(alkyl)carbene Ruthenium Catalyst for Ethenolysis of Ethyl Oleate: Selectivity Is on Target
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DOI: 10.1021/acsomega.8b03119
Abstract: A wide set of 65 diverse Ru metathesis catalysts was investigated in the ethenolysis reaction of biosourced ethyl oleate to allow the comparison between the catalyst structure and its activity and selectivity. Handling of the… read more here.
Keywords: ethyl oleate; ethenolysis; looking noncyclic; noncyclic amino ... See more keywords