Overcoming the Deallylation Problem: Palladium(II)-Catalyzed Chemo-, Regio-, and Stereoselective Allylic Oxidation of Aryl Allyl Ether, Amine, and Amino Acids.
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DOI: 10.1021/acs.orglett.0c02465
Abstract: We report herein a Pd(II)/bis-sulfoxide-catalyzed intramolecular allylic C-H acetoxylation of aryl allyl ether, amine, and amino acids with the retention of a labile allyl moiety. Mechanistically, the reaction proceeds through a distinct double-bond isomerization from… read more here.
Keywords: aryl allyl; allyl ether; amino acids; amine amino ... See more keywords
Light-Induced Programmable 2D Ordered Patterns Based on a Hyperbranched Poly(ether amine) (hPEA)-Functionalized Graphene Film.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.0c15099
Abstract: Dynamic complex surface topography with ordered and tunable morphologies, which can provide on-demand control of surface properties to realize smart surfaces, is gaining much attention yet remains challenging in terms of fabrication. Here, a facile,… read more here.
Keywords: ordered patterns; hyperbranched poly; ether amine; amine hpea ... See more keywords