Oxime Ether Synthesis through O-H Functionalization of Oximes with Diazo Esters under Blue LED Irradiation.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c02555
Abstract: A green and sustainable oxime ether formation method via the visible-light-promoted O-H functionalization of oximes with diazo esters is described. The reaction occurs under very mild conditions (catalyst- and additive-free) with a high yield and… read more here.
Keywords: functionalization oximes; oxime ether; diazo esters; ether synthesis ... See more keywords
Experimental validation of pressure swing regeneration for faster cycling in sorption enhanced dimethyl ether synthesis.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc06093c
Abstract: Sorption enhanced dimethyl ether synthesis (SEDMES) is a novel DME production route from CO2-rich feedstocks. In situ water removal by adsorption results in high single-pass conversions, thereby circumventing the disadvantages of conventional routes, such as… read more here.
Keywords: dimethyl ether; regeneration; swing regeneration; ether synthesis ... See more keywords
Mechanism, kinetics and selectivity of a Williamson ether synthesis: elucidation under different reaction conditions
Sign Up to like & getrecommendations! Published in 2021 at "Reaction Chemistry and Engineering"
DOI: 10.1039/d0re00437e
Abstract: The best route to uncover the mechanism of chemical reactions remains a topic of intense debate. In this work, we deploy a three-faceted approach that combines experimental probing, detailed kinetic modelling and quantum-mechanical calculations for… read more here.
Keywords: alkylation; ether synthesis; reaction; selectivity ... See more keywords