Photocatalytic Reductive Formation of α-Tertiary Ethers from Ketals.
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DOI: 10.1021/acs.orglett.9b02273
Abstract: A general photocatalytic reductive strategy for the construction of unsymmetrical α-tertiary dialkyl ethers is reported. By merging Lewis acid-mediated ketal activation and visible-light photocatalytic reduction, in situ-generated α-alkoxy radicals were found to engage in addition… read more here.
Keywords: methodology; photocatalytic reductive; ethers ketals; tertiary ethers ... See more keywords