Thermal Decomposition of Ethyl Diazoacetate in Microtube Reactor: A Kinetics Study
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DOI: 10.1021/acsomega.8b01521
Abstract: Ethyl diazoacetate (EDA) commonly experiences intensive decomposition as well as complex conversion concerning safety and efficiency. In this work, a careful kinetics study on the thermal decomposition of EDA was isothermally conducted in a microtube… read more here.
Keywords: kinetics study; thermal decomposition; microtube reactor; ethyl diazoacetate ... See more keywords
Mechanistic studies of the copolymerization between ethyl diazoacetate and cinnamaldehyde
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DOI: 10.1039/c6py02126c
Abstract: The Ndiazo,C3-diradical of diazomethane (˙NN–H2C˙) is a resonance structure with 1,3-dipole form. And alkyl diazoacetate (ethyl diazoacetate, EDA) can interact with α,β-unsaturated aldehyde (cinnamaldehyde, CA) without any catalyst to compose the Ndiazo,C5- and Ndiazo,C8-diradicals, which… read more here.
Keywords: cinnamaldehyde; copolymerization ethyl; diazoacetate; studies copolymerization ... See more keywords
Olefination of Aldehydes with Ethyl Diazoacetate Catalyzed by Nitrogen-Doped Carbon-Supported Metal
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DOI: 10.1246/cl.210355
Abstract: Nitrogen-doped carbon-supported Co/Cu bimetallic catalysts were found to catalyze olefination of aldehydes with ethyl diazoacetate. In the presence of triaryl phosphine with electron-withdrawing gr... read more here.
Keywords: olefination aldehydes; doped carbon; nitrogen doped; ethyl diazoacetate ... See more keywords