Copper-Catalyzed Enantioselective Hydrosilylation of Allenes to Access Axially Chiral (Cyclohexylidene)ethyl Silanes.
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DOI: 10.1021/acs.orglett.2c02359
Abstract: A novel strategy of copper-catalyzed regio- and enantioselective hydrosilylation of 4-substituted vinylidenecyclohexanes with silanes was developed. In this protocol, various allenes and silanes were used to afford the corresponding (cyclohexylidene)ethyl silanes in moderate to high… read more here.
Keywords: copper catalyzed; cyclohexylidene ethyl; ethyl silanes; enantioselective hydrosilylation ... See more keywords