Ultra-Highly Active Ni-Doped MOF-5 Heterogeneous Catalysts for Ethylene Dimerization.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202301235
Abstract: Here, an ultra-highly active Ni-MOF-5 catalyst with high Ni loading for ethylene dimerization is reported. The Ni-MOF-5 catalysts are synthesized by a facile one-pot co-precipitation method at room temperature, where Ni2+ replaces Zn2+ in MOF-5.… read more here.
Keywords: active doped; heterogeneous catalysts; ethylene dimerization; highly active ... See more keywords
Cooperativity in Highly Active Ethylene Dimerization by Dinuclear Nickel Complexes Bearing a Bifunctional PN Ligand
Sign Up to like & getrecommendations! Published in 2021 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00683
Abstract: In order to examine the possibility to promote cooperative effects on catalytic activity and selectivity in ethylene dimerization through ligand design, the bisphosphino-iminato ligands syn-L and a... read more here.
Keywords: ethylene; highly active; ligand; ethylene dimerization ... See more keywords
Selectivity Effects on N,N,N′-Cobalt Catalyzed Ethylene Dimerization/Trimerization Dictated through Choice of Aluminoxane Cocatalyst
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00924
Abstract: The cobalt(II) chloride complexes, [2-(C7H4N2H)-8-(ArN)C10H8N]CoCl2 (Ar = 2,6-Me2C6H3 Co1; 2,6-Et2C6H3 Co2; 2,6-i-Pr2C6H3 Co3; 2,4,6-Me3C6H2 Co4; 2,6-Et2-4-MeC6H2 Co5; 2,4,6-t-Bu3C6H2 Co6), have each been prepared by a one-pot template reaction of 2-benzoimidazolyl-5,6,7-trihydroquinolin-8-one with the corresponding aniline in… read more here.
Keywords: dimerization trimerization; ethylene dimerization; dimerization; selectivity ... See more keywords
Exploration of Homogeneous Ethylene Dimerization Mediated by Tungsten Mono(imido) Complexes
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b02201
Abstract: In combination with EtAlCl2, complexes {[WCl3(μ-Cl)(N-2,6-iPr2C6H3)]2}, [WCl4(NR)(thf)] (R = Et, iPr, cHx, Ph, 2,6-iPr2C6H3, 4-F-C6H4, and 2,4,6-F3-C6H2), and [WCl2(NR′)(PMe3)3] (R′ = Ph, 2,6-iPr2C6H3) were all productive ethylene dimerization pre-catalysts, giving turnover numbers (TONs) in the… read more here.
Keywords: imido complexes; ethylene dimerization; tungsten mono; mono imido ... See more keywords
Highly Selective Heterogeneous Ethylene Dimerization with a Scalable and Chemically Robust MOF Catalyst
Sign Up to like & getrecommendations! Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b05703
Abstract: Metal–organic frameworks (MOFs) hold great promise as structurally tunable catalysts capable of high selectivity in the solid state, yet their comparatively high cost and often limited stability remain significant concerns for their commercialization as heterogeneous… read more here.
Keywords: highly selective; heterogeneous ethylene; ethylene dimerization; dimerization ... See more keywords
2-(N,N-Diethylaminomethyl)-6,7-trihydroquinolinyl-8-ylideneamine-Ni(ii) chlorides: application in ethylene dimerization and trimerization
Sign Up to like & getrecommendations! Published in 2020 at "New Journal of Chemistry"
DOI: 10.1039/d0nj04003g
Abstract: A series of Ni(II) complexes with the general formula [2-((NEt2)Me)-8-{N(Ar)}C9H8N]NiCl2, where Ar = 2,6-Me2C6H3 in Ni1, 2,6-Et2C6H3 in Ni2, 2,6-i-Pr2C6H3 in Ni3, 2,4,6-Me3C6H2 in Ni4, 2,6-Et2-4-MeC6H2 in Ni5, and 2,4,6-t-Bu3C6H2 in Ni6, has been prepared… read more here.
Keywords: diethylaminomethyl; diethylaminomethyl trihydroquinolinyl; trihydroquinolinyl ylideneamine; ylideneamine chlorides ... See more keywords