Preparation and in situ chain-end-functionalization of branched ethylene oligomers by monosubstituted α-diimine nickel catalysts
Sign Up to like & getrecommendations! Published in 2019 at "Polymer Chemistry"
DOI: 10.1039/c9py00433e
Abstract: Chain-end-functionalization of (highly) branched ethylene oligomers was achieved in situ with the most/least bulky α-diimine nickel catalysts for the first time. read more here.
Keywords: chain end; nickel catalysts; end functionalization; diimine nickel ... See more keywords
Ethylene (co) oligomerization using iminopyridyl Ni(II) and Pd(II) complexes bearing benzocycloalkyl moieties to access hyperbranched ethylene oligomers and ethylene-MA co-oligomers
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.961426
Abstract: Hyperbranched ethylene oligomers and polar functionalized co-oligomers synthesized via ethylene chain walking (co) oligomerization is a very attractive strategy. In this study, a series of dibenzhydryl iminopyridyl ligands with benzocycloalkyl and naphthyl moieties and the… read more here.
Keywords: oligomers ethylene; oligomerization; ethylene oligomers; hyperbranched ethylene ... See more keywords