Methylene-Bridged Bisphosphine Monoxide Ligands for Palladium-Catalyzed Copolymerization of Ethylene and Polar Monomers
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DOI: 10.1021/acsmacrolett.8b00034
Abstract: A series of palladium complexes bearing a bisphosphine monoxide with a methylene linker, that is, [κ2-P,O-(R12P)CH2P(O)R22]PdMe(2,6-lutidine)][BArF4] (Pd/BPMO), were synthesized and evaluated as catalysts for the homopolymerization of ethylene and the copolymerization of ethylene and polar… read more here.
Keywords: ethylene polar; polar monomers; copolymerization ethylene; copolymerization ... See more keywords
Recent Advances in the Copolymerization of Ethylene with Polar Comonomers by Nickel Catalysts
Sign Up to like & getrecommendations! Published in 2022 at "Polymers"
DOI: 10.3390/polym14183809
Abstract: The less-expensive and earth-abundant nickel catalyst is highly promising in the copolymerization of ethylene with polar monomers and has thus attracted increasing attention in both industry and academia. Herein, we have summarized the recent advancements… read more here.
Keywords: nickel catalysts; advances copolymerization; copolymerization ethylene; copolymerization ... See more keywords