Selective, Stable Production of Ethylene Using a Pulsed Cu-Based Electrode.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c01230
Abstract: Ethylene (C2H4) is an important product in carbon dioxide electroreduction (CO2RR) because of the essential role it plays in chemical industry. While several strategies have been proposed to tune the selectivity of Cu-based catalysts in… read more here.
Keywords: c2h4; ethylene; selective stable; stable production ... See more keywords
Conversion of methane to ethylene using an Ir complex and phosphorus ylide as a methylene transfer reagent.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c8cc08761j
Abstract: Cp*(Me3P)Ir(CH3)(OTf), a complex known to reversibly activate CH4 and other hydrocarbons under mild conditions, reacts with the phosphorus ylide H2CPPh3 in THF to afford two major species [Cp*(Me3P)(Ph3P)Ir(CH2CH3)][OTf] and [Cp*(Me3P)Ir(H)(η2-CH2CH2)][OTf]. Insertion of the ylide methylene… read more here.
Keywords: methane ethylene; phosphorus ylide; ylide methylene; conversion methane ... See more keywords