Synthesis, characterization and phenoxazinone synthase mimicking activity of cobalt(III) Schiff base complexes
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DOI: 10.1016/j.poly.2016.10.027
Abstract: Abstract Three new mononuclear cobalt(III) complexes, [Co(L1)2]ClO4·2H2O (1) {HL1 = 2((2(2-hydroxyethylamino)ethylimino)methyl)-6-methoxyphenol}, [Co(L2)(acna)(N3)] (2) {HL2 = 2((2(2-hydroxyethylamino)ethylimino)methyl)-6-ethoxyphenol, Hacna = 2-acetyl-1-naphthol} and [Co(L3)(bzan)(N3)] (3) {HL3 = 1((2(diethylamino)ethylimino)methyl)naphthalen-2-ol, Hbzan = 1-benzoylacetone} were prepared and characterized by elemental and spectral analysis. The structures of all complexes were confirmed by… read more here.
Keywords: cobalt; characterization phenoxazinone; ethylimino methyl; cobalt iii ... See more keywords
Tetranuclear Copper(II) Complexes Derived from 5-Bromo-2-((2-(2-hydroxyethylamino)ethylimino)methyl)phenol: Synthesis, Characterization, Crystal Structures and Catalytic Oxidation of Olefins.
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DOI: 10.17344/acsi.2022.7530
Abstract: An acetate bridged tetranuclear copper(II) complex, [Cu4L2(μ2-η1:η1-CH3COO)6(CH3OH)2] (1), and a chloride, phenolate and azide co-bridged tetranuclear copper(II) complex, [Cu4L2Cl2(μ-Cl)2(μ1,1-N3)2]2CH3OH (2), where L is the deprotonated form of the Schiff base 5-bromo-2-((2-(2-hydroxyethylamino)ethylimino)methyl)phenol (HL), have been synthesized… read more here.
Keywords: crystal; tetranuclear copper; copper; ethylimino methyl ... See more keywords