Isolation of Silacycles from the Reactions of a Monochlorosilylene LSi(:)Cl (L = PhC(NtBu)2) with Ethynyl Lithium Salts.
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DOI: 10.1021/acs.inorgchem.2c01762
Abstract: The reactions of amidinate silylene chloride LSi(:)Cl (L = PhC(NtBu)2) with TMS- and Ph-ethynyl lithium salts gave rise to silacycles 1 and 4, respectively. The formation of 1 and 4 may undergo cyclo-condensations of transient… read more here.
Keywords: lithium salts; lsi phc; phc ntbu; ethynyl lithium ... See more keywords