Evaluating f-Orbital Participation in the UV═E Multiple Bonds of [U(E)(NR2)3] (E = O, NSiMe3, NAd; R = SiMe3).
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DOI: 10.1021/acs.inorgchem.3c00455
Abstract: The reaction of 1 equiv of 1-azidoadamantane with [UIII(NR2)3] (R = SiMe3) in Et2O results in the formation of [UV(NR2)3(NAd)] (1, Ad = 1-adamantyl) in good yields. The electronic structure of 1, as well as… read more here.
Keywords: spectroscopy; orbital participation; electronic structure; sime3 ... See more keywords