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First Example of Fluorinated Phenanthroline Diamides: Synthesis, Structural Study, and Complexation with Lanthanoids

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Published in 2022 at "Molecules"

DOI: 10.3390/molecules27154705

Abstract: An efficient approach to the synthesis of diamides of 4,7-difluoro-1,10-phenanthroline-2,9-dicarboxylic acid was elaborated. Direct nucleophilic substitution with 4,7-dichloro-1,10-phenanthroline precursors opened access to difluoro derivatives in high yield. As a result, four new fluorinated ligands were… read more here.

Keywords: first example; phenanthroline; spectroscopy; phenanthroline diamides ... See more keywords