Octahedral Ruthenium Complex with Exclusive Metal-Centered Chirality for Highly Effective Asymmetric Catalysis.
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DOI: 10.1021/jacs.7b01098
Abstract: A novel ruthenium catalyst is introduced which contains solely achiral ligands and acquires its chirality entirely from octahedral centrochirality. The configurationally stable catalyst is demonstrated to catalyze the alkynylation of trifluoromethyl ketones with very high… read more here.
Keywords: ruthenium; complex exclusive; chirality; exclusive metal ... See more keywords