Modified synthesis of Ru–Rh heterobimetallic metallacarboranes based on ruthenium exo-nido complexes and not accompanied by exo-nido → closo rearrangement
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DOI: 10.1016/j.mencom.2019.01.023
Abstract: The use of improved protocol for the reaction of rhodium acetylacetonate complexes (diene)RhAcac [diene is 1,5-cyclooctadiene or norbornadiene] with exo-nido-ruthenacarboranes 5,6,10-[RuCl(PPh3)2]-5,6,10-(μ-H)3-10-H-7,8-R2-7,8-C2B8H6 (R = H or Me) allowed us to synthesize three new binuclear complexes, wherein… read more here.
Keywords: nido; exo nido; synthesis heterobimetallic; ruthenium ... See more keywords