A naphthalene-fused dimer of an anti-aromatic expanded isophlorin.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc04050d
Abstract: We report the first synthesis of a covalent expanded isophlorin dimer from two 24-π doubly S-confused sapphyrin-like pentathiaisophlorins. It exhibits marginal peripheral aromaticity rather than strong global diatropicity or paratropicity and weak intermacrocycle electronic communication.… read more here.
Keywords: dimer anti; anti aromatic; naphthalene fused; expanded isophlorin ... See more keywords
Non-planar core-modified dibenzi expanded isophlorin
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Porphyrins and Phthalocyanines"
DOI: 10.1142/s1088424619501050
Abstract: The role of aromatic subunits is crucial to the structural and electronic properties of isophlorin and its expanded derivatives. Herein we describe the effect of benzene ring substitution in a 32π ... read more here.
Keywords: non planar; dibenzi expanded; modified dibenzi; planar core ... See more keywords