Expanding the chemistry of borates with functional [BO2]− anions
Sign Up to like & getrecommendations! Published in 2021 at "Nature Communications"
DOI: 10.1038/s41467-021-22835-4
Abstract: More than 3900 crystalline borates, including borate minerals and synthetic inorganic borates, in addition to a wealth of industrially-important boron-containing glasses, have been discovered and characterized. Of these compounds, 99.9 % contain only the traditional… read more here.
Keywords: borates functional; functional bo2; expanding chemistry; chemistry ... See more keywords
Expanding the chemistry of ring-fused 1,4-diphosphinines by stable mono anion formation.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc08158a
Abstract: A new sulfur-enriched tricyclic 1,4-diphosphinine (2) was synthesized and novel reactivity studies on the phosphorus heterocycle were performed: a weak anionic nucleophile (KHMDS) adds selectively thus forming a stable anionic 1,4-diphosphinine derivative (3b) which was… read more here.
Keywords: fused diphosphinines; ring fused; expanding chemistry; chemistry ... See more keywords