Experimental and kinetic modeling investigation on anisole pyrolysis: Implications on phenoxy and cyclopentadienyl chemistry
Sign Up to like & getrecommendations! Published in 2019 at "Combustion and Flame"
DOI: 10.1016/j.combustflame.2018.12.028
Abstract: Abstract In this work, the flow reactor pyrolysis of anisole was studied at pressures of 0.04 and 1 atm and temperatures from 850 to 1160 K. Comprehensive speciation was achieved using synchrotron vacuum ultraviolet photoionization mass… read more here.
Keywords: kinetic modeling; experimental kinetic; chemistry; pyrolysis ... See more keywords
Experimental and kinetic modeling study on 1,3-cyclopentadiene oxidation and pyrolysis
Sign Up to like & getrecommendations! Published in 2020 at "Combustion and Flame"
DOI: 10.1016/j.combustflame.2019.10.032
Abstract: Abstract The oxidation of 1,3-cyclopentadiene (c-C5H6), a key intermediate formed in the combustion of aromatic and cyclic hydrocarbon fuels and formation of polycyclic aromatic hydrocarbons (PAHs), was studied in a jet-stirred reactor (JSR) under the… read more here.
Keywords: kinetic modeling; modeling study; oxidation; experimental kinetic ... See more keywords
Detailed experimental and kinetic modeling study of toluene/C2 pyrolysis in a single-pulse shock tube
Sign Up to like & getrecommendations! Published in 2021 at "Combustion and Flame"
DOI: 10.1016/j.combustflame.2020.11.044
Abstract: Abstract A combined experimental and kinetic modeling study is carried out to explore the influences of acetylene and ethylene addition on the species formation from toluene pyrolysis. Experiments are conducted separately with four different argon-diluted… read more here.
Keywords: kinetic modeling; modeling study; pyrolysis; experimental kinetic ... See more keywords
Experimental and kinetic study on the laminar burning velocities of NH3 mixing with CH3OH and C2H5OH in premixed flames
Sign Up to like & getrecommendations! Published in 2021 at "Combustion and Flame"
DOI: 10.1016/j.combustflame.2021.02.038
Abstract: Abstract Ammonia (NH3) is a promising carbon-free alternative fuel, and blending NH3 with other more active fuels can enhance the low burning rate of pure NH3 flames, which makes it more compatible with existing combustors.… read more here.
Keywords: burning velocities; laminar burning; velocities nh3; kinetic study ... See more keywords
An experimental and kinetic modeling study of NOx sensitization on methane autoignition and oxidation
Sign Up to like & getrecommendations! Published in 2021 at "Combustion and Flame"
DOI: 10.1016/j.combustflame.2021.111746
Abstract: Abstract An experimental and kinetic modeling study of the influence of NOx (i.e. NO2, NO and N2O) addition on the ignition behavior of methane/‘air’ mixtures is performed. Ignition delay time measurements are taken in a… read more here.
Keywords: kinetic modeling; modeling study; experimental kinetic; ignition ... See more keywords
A Comprehensive Experimental and Kinetic Study of Laminar Flame Characteristics of H2 and CO Addition to Oxygenated Gasoline
Sign Up to like & getrecommendations! Published in 2021 at "Energy & Fuels"
DOI: 10.1021/acs.energyfuels.1c01916
Abstract: The paper is based on work supported by the Saudi Aramco Research and Development Center FUELCOM2 program under Master Research Agreement Number 6600024505/01. FUELCOM (Fuel Combustion for Advanced Engines) is a collaborative research undertaking between… read more here.
Keywords: flame characteristics; comprehensive experimental; experimental kinetic; kinetic study ... See more keywords
Experimental and Kinetic Modeling Studies of Methyl 2-Furoate Pyrolysis at Atmospheric Pressure
Sign Up to like & getrecommendations! Published in 2019 at "Energy & Fuels"
DOI: 10.1021/acs.energyfuels.9b00367
Abstract: Methyl 2-furoate (FAME2) pyrolysis was studied experimentally on a flow reactor in the temperature range of 879-1107 K and at the pressure of 760 Torr using synchrotron vacuum ultraviolet photoionization mass spectrometry. Several important intermediates were… read more here.
Keywords: methyl furoate; experimental kinetic; pressure; pyrolysis ... See more keywords
The Challenge of Reproducing with Calculations Raw Experimental Kinetic Data for an Organic Reaction.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c00367
Abstract: DFT calculations and microkinetic simulations are applied to the reproduction of previously reported experimental results on the evolution of product concentration versus time in the condensation reaction of n-butylamine and benzaldehyde. The mechanism is complicated… read more here.
Keywords: experimental kinetic; calculations raw; reaction; reproducing calculations ... See more keywords
Ylidenenorbornadiene Carboxylates: Experimental Kinetic Analysis of a Nucleophile-Induced Fragmentation Reaction.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00630
Abstract: Ylidenenorbornadienes (YNDs), prepared by [4 + 2] cycloadditions between fulvenes and acetylene carboxylates, react with beta-mercaptoethanol to yield a mixture of four diastereomers. These four diastereomers fragment via a retro-[4 + 2] cycloaddition at differing… read more here.
Keywords: fragmentation; ylidenenorbornadiene carboxylates; experimental kinetic; analysis nucleophile ... See more keywords
Experimental and Kinetic Studies of Ethylene Glycol Autoignition at High Temperatures
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c00275
Abstract: As one of the simplest polyols with chemical properties of alcohol, ethylene glycol is considered as a renewable energy source and a model fuel for pyrolysis oil. In this work, autoignition characteristics of ethylene glycol… read more here.
Keywords: kinetic studies; ethylene glycol; glycol; studies ethylene ... See more keywords
Experimental and Kinetic Modeling Study on High-Temperature Autoignition of Cyclohexene
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DOI: 10.1021/acsomega.2c02229
Abstract: Cyclohexene is an important intermediate during the oxidation of cycloalkanes, which comprise a significant portion of real fuels. Thus, experimental data sets and kinetic models of cyclohexene play an important role in the understanding of… read more here.
Keywords: study high; kinetic modeling; experimental kinetic; temperature ... See more keywords