Symmetry Breaking in a Triferrous Extended Metal Atom Chain
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.4c02752
Abstract: Semilocal and random phase approximation (RPA) density functional theory (DFT) and complete active space (CASSCF + NEVPT2) methodologies were applied to investigate a new class of extended metal atom chain (EMAC) complexes. A novel triferrous… read more here.
Keywords: atom chain; metal atom; extended metal; symmetry breaking ... See more keywords
The structure of a pentachromium(II) extended metal atom chain at 3 K: Cotton's conjecture proven.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt03103e
Abstract: We provide definitive experimental proof that the archetypal string-like compound [Cr5(tpda)4(NCS)2] has alternating long and short Cr-Cr separations in the solid state, as conjectured by F. A. Cotton, rather than essentially equally spaced Cr atoms,… read more here.
Keywords: structure pentachromium; pentachromium extended; atom chain; cotton ... See more keywords