Extreme g-Tensor Anisotropy and Its Insensitivity to Structural Distortions in a Family of Linear Two-Coordinate Ni(I) Bis-N-heterocyclic Carbene Complexes.
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DOI: 10.1021/acs.inorgchem.1c02413
Abstract: We report a new series of homoleptic Ni(I) bis-N-heterocyclic carbene complexes with a range of torsion angles between the two ligands from 68° to 90°. Electron paramagnetic resonance measurements revealed a strongly anisotropic g-tensor in… read more here.
Keywords: carbene complexes; extreme tensor; bis heterocyclic; heterocyclic carbene ... See more keywords