Linear Eyring Plots Conceal a Change in the Rate-Limiting Step in an Enzyme Reaction
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DOI: 10.1021/acs.biochem.8b01099
Abstract: The temperature dependence of psychrophilic and mesophilic (R)-3-hydroxybutyrate dehydrogenase steady-state rates yields nonlinear and linear Eyring plots, respectively. Solvent viscosity effects and multiple- and single-turnover pre-steady-state kinetics demonstrate that while product release is rate-limiting at… read more here.
Keywords: step; rate limiting; eyring plots; rate ... See more keywords