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F10BINOL-derived chiral phosphoric acid-catalyzed enantioselective carbonyl-ene reaction: theoretical elucidation of stereochemical outcomes† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03587c

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0 Published in 2019 at "Chemical Science"

DOI: 10.1039/c8sc03587c

Abstract: An enantioselective carbonyl-ene reaction of 1,1-disubstituted olefins with ethyl glyoxylate was accomplished using an F10BINOL-derived chiral phosphoric acid of which the perfluoro-binaphthyl skeleton is beneficial not only for adopting high catalytic activity but also for… read more here.

Keywords: carbonyl ene; f10binol derived; derived chiral; chiral phosphoric ... See more keywords