Exceptionally Robust Face-Sharing Motifs Enable Efficient and Durable Water Oxidation.
Sign Up to like & getrecommendations! Published in 2021 at "Advanced materials"
DOI: 10.1002/adma.202103392
Abstract: Corner-sharing oxides usually suffer from structural reconstruction during the bottleneck oxygen-evolution reaction (OER) in water electrolysis. Therefore, introducing dynamically stable active sites in an alternative structure is urgent but challenging. Here, 1D 5H-polytype Ba5 Bi0.25… read more here.
Keywords: co3 feo14; face sharing; ba5 bi0; sharing motifs ... See more keywords
Molecular mechanism of formation of the face-sharing double cages in structure-I methane hydrate
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2017.11.013
Abstract: Abstract Despite the potential applications and ubiquity of clathrate hydrates, the molecular mechanism of formation of these compounds is not yet well-understood. In this work, the formation mechanism of the face-sharing double cages in structure-I… read more here.
Keywords: mechanism; mechanism formation; face sharing; formation ... See more keywords
Enhanced hydrogen evolution from the face-sharing [RuO6] octahedral motif
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Energy Chemistry"
DOI: 10.1016/j.jechem.2020.08.015
Abstract: Abstract Hampered by the ambiguous mechanism of hydrogen evolution reaction (HER) in basic media, the exploration of highly efficient catalytically active sites for alkaline HER is of significance. Herein, a metal oxide Sr4Ru2O9 engineering a… read more here.
Keywords: hydrogen evolution; face sharing; sharing ruo6;
Hexagonal Perovskites as Quantum Materials.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.0c00622
Abstract: Hexagonal perovskites, in contrast to the more familiar perovskites, when oxides, allow for face-sharing of metal-oxygen octahedra or trigonal prisms within their structural frameworks. This results in dimers, trimers, tetramers, or longer fragments of chains… read more here.
Keywords: oxide perovskites; face sharing; hexagonal perovskites; metal ... See more keywords
Face-Sharing Archimedean Solids Stacking for the Construction of Mixed-Ligand Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b05580
Abstract: Reticular chemistry has been an important guiding principle for the design of metal-organic frameworks (MOFs). This approach utilizes discrete building units (molecules and clusters) which are connected through strong bonds into extended networks assisted by… read more here.
Keywords: metal organic; face sharing; organic frameworks; archimedean solids ... See more keywords
Structural insights into T2-cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ6 ligands: Na3ZnMIIIQ4 (MIII = In, Ga; Q = S, Se).
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03281e
Abstract: A series of quaternary chalcogenides, Na3ZnMIIIQ4 (MIII = In, Ga; Q = S, Se), were successfully synthesized for the first time through a high temperature solid-state reaction method. All of them exhibit similar structures and… read more here.
Keywords: containing chalcogenides; edge face; connection modes; connection ... See more keywords
Novel nickel–cobalt phosphite with face-sharing octahedra derived electrocatalyst for efficient water splitting
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic Chemistry Frontiers"
DOI: 10.1039/c9qi00370c
Abstract: Nickel–cobalt phosphite (CoNiPO) including local structural motifs with face-sharing octahedra shows excellent OER activity. The derivatized electrocatalyst (NiP2@CoNiPO) exhibits high HER activity. DFT calculations indicated the super-exchange effect in CoNiPO can adjust local electronic structure… read more here.
Keywords: nickel cobalt; cobalt phosphite; face sharing; novel nickel ... See more keywords
Superexchange interactions between spin-orbit-coupled j≈1/2 ions in oxides with face-sharing ligand octahedra
Sign Up to like & getrecommendations! Published in 2019 at "Physical Review B"
DOI: 10.1103/physrevb.99.115119
Abstract: Using ab initio wave-function-based calculations, we provide valuable insights with regard to the magnetic exchange in $5d$ and $4d$ oxides with face-sharing ligand octahedra, ${\mathrm{BaIrO}}_{3}$ and ${\mathrm{BaRhO}}_{3}$. Surprisingly strong antiferromagnetic Heisenberg interactions as large as… read more here.
Keywords: oxides face; ligand octahedra; face sharing; sharing ligand ... See more keywords