The Different Faces of Photoredox Catalysts: Visible-Light-Mediated Atom Transfer Radical Addition (ATRA) Reactions of Perfluoroalkyl Iodides with Styrenes and Phenylacetylenes
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DOI: 10.1021/acscatal.8b00847
Abstract: A photoredox-catalyzed procedure for the iodoperfluoroalkylation of styrenes and phenylacetylenes using readily available copper phenanthroline catalyst is reported. In contrast to commonly employed [Ru(bpy)3]Cl2, [Ru(phen)3]Cl2 or fac-Ir(ppy)3, [Cu(dap)2]Cl is capable to convert styrenes to the… read more here.
Keywords: different faces; catalysts visible; transfer; photoredox catalysts ... See more keywords